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Read e-book online Enantioselective Chemical Synthesis. Methods, Logic, and PDF

By Elias J. Corey, Laszlo Kurti

ISBN-10: 0615395155

ISBN-13: 9780615395159

Written through world-renowned and best-selling specialists, Nobel Laureate E. J. Corey and Laszlo Kurti, Enantioselective Chemical Synthesis bargains an authoritative and accomplished review of the field’s growth; the approaches and instruments for key formations; destiny improvement for complicated, stereocontrolled (enantiomeric or diastereoisomeric) molecules; and invaluable examples of multi-step syntheses. using a color-coded scheme to demonstrate chemical changes, Enantioselective Chemical Synthesis presents transparent clarification and counsel via important asymmetrical syntheses and perception into the following steps for the sector. Researchers, execs, and lecturers will reap the benefits of this beneficial, thorough, and precise source.

  • In half I, the authors current sincerely, comprehensively and concisely the main priceless enantioselective tactics on hand to artificial chemists.
  • Part II offers an intensive dialogue of the main logical how you can observe those new enantioselective how to the making plans of syntheses of stereochemically complicated molecules. This hitherto missed zone is key for the development of enantioselective synthesis to a extra rational and strong point.
  • Part III describes intimately many response sequences that have been used effectively for the development of a wide selection of complicated aim molecules
  • Clearly explains stereochemical synthesis in concept and practice
  • Provides a handy gizmo field for scientists wishing to appreciate and follow chiral chemical synthesis
  • Describes nearly 50 actual existence examples of uneven synthesis in perform and examines how the chiral facilities have been brought at key artificial stages

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Additional info for Enantioselective Chemical Synthesis. Methods, Logic, and Practice

Example text

Walker, F. J. & Woodard, S. S. Stereo and regioselective openings of chiral 2,3-epoxy alcohols. Versatile routes to optically pure natural products and drugs. Unusual kinetic resolutions. Pure Appl. Chem. 1983, 55, 589-604; (c) Hanson, R. M. The synthetic methodology of nonracemic glycidol and related 2,3-epoxy alcohols. Chem. Rev. 1991, 91, 437-476; (d) Pena, P. C. A. & Roberts, S. M. The chemistry of epoxy alcohols. Curr. Org. Chem. 2003, 7, 555-571. Martin, V. , Woodard, S. , Ikeda, M. & Sharpless, K.

Total synthesis of venustatriol. Tetrahedron Lett. 1988, 29, 3171-3174. (a) Sharpless, K. , Woodard, S. S. & Finn, M. G. On the mechanism of titanium-tartrate-catalyzed asymmetric epoxidation. Pure Appl. Chem. 1983, 55, 1823-1836; (b) Woodard, S. , Finn, M. G. & Sharpless, K. B. Mechanism of asymmetric epoxidation. 1. Kinetics. J. Am. Chem. Soc. 1991, 113, 106-113; (c) Finn, M. G. & Sharpless, K. B. Mechanism of asymmetric epoxidation. 2. Catalyst structure. J. Am. Chem. Soc. 1991, 113, 113-126; (d) Potvin, P.

Sharpless, K. B. Mechanism of asymmetric epoxidation. 2. Catalyst structure. J. Am. Chem. Soc. 1991, 113, 113-126; (d) Potvin, P. G. & Bianchet, S. The nature of the Katsuki-Sharpless asymmetric epoxidation catalyst. J. Org. Chem. 1992, 57, 6629-6635. (a) Corey, E. J. On the origin of enantioselectivity in the KatsukiSharpless epoxidation procedure. J. Org. Chem. , Shen, J. , Luo, X. , Tan, X. , Chen, K. , Ji, R. Y. & Jiang, H. L.

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Enantioselective Chemical Synthesis. Methods, Logic, and Practice by Elias J. Corey, Laszlo Kurti

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